If you drive your car for any length of time then sooner or later your alloy wheels will collect grime. The front wheels will be worse because of the brake dust. That is, as you brake, most of the work is being done by your front brakes, as obviously the weight transfers to the front of the car as you brake.
With normal carwash it does not come off very easily, and is very greasy in nature. Even if you go to one of those DIY carwashes and use the foaming brush even then it doesn’t come off very well.
So use oven cleaner. Spray oven cleaner onto it, leave it for a couple of minutes, and it will just wipe straight off. At the DIY carwash, it will just blast off with the high pressure water cleaner